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Luke Skywalker - The good guy in the movie. He risks his life for Han and Leia.
Han Solo - He is another good guy from Star Wars. He is the pilot of the Millenium Falcon.
Princess Leia - She is the princess in the movie. some of her servants (rebels, also good guys) stole the plans on how to detroy the first Death Star.
Darth Vader - He is a bad guy. He is Luke's father. Luke finds this out when they are escaping from Darth Vader on Cloud City.
Ben Kanobe (O.B. Wan Kanobe) - He helps Luke Skywalker in the first movie when Luke has been hurt by a sand people.
Yoda - He is a funny looking creature who helps Luke Skywalker become a Jedi (a good fighter that uses the Force to defeat evil).
There are many more interesting characters in the movie, and you should definitely watch it and find out who they are!
Check out the Star Wars website and in the Star Wars website you'll have a blast.