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Perturbation and Degeneracy in Mechanics


    If a polynomial has multiple roots, we may modify its coefficients a little bit so that all its roots become simple. Similarly, for the Schrödinger equation, we may perturb the Hamiltonian operator a little bit and remove the degeneracy of its eigenvalues.
  1. First excited states of helium
    1. The reason for the removal of the l degeneracy [Lev2, p.271, l.-16-l.-3].
    2. The reason for the removal of the exchange degeneracy [Lev2, p.271, l.-2-p.272, l.11].