Activity of HRh(CO)(PPh3)3 catalyst in hydroformylation
of Allyl Alcohol :effect of second immiscible liquid phase : R.M.
Deshpande, S.S. Divekar, B.M. Bhanage and R.V. Chaudhari.; J. Mol. Catal. 75, L19-L22, (1992) abstract
Solvent effect in kinetics of hydroformylation of 1hexene using HRh(CO)(PPh3)3 catalyst: R.M. Deshpande, B.M. Bhanage, S.S. Divekar and R.V. Chaudhari. : J. Mol. Catal.77, L13-L17, (1992)abstract
Solvent effects in hydroformylation of 1octene using HRh(CO)(PPh3)3 catalyst : Effect of PPh3 addition on the rate of reaction: R.M.Deshpande, B.M.Bhanage,S.S.Divekar and R.V. Chaudhari ; J. Mol. Catal.78, L37-L40, (1993)abstract
Selectivity in Hydroformylation of 1-decene by homogeneous catalysis:
S.S. Divekar, B.M. Bhanage, R.M. Deshpande, R.V. Gholap and R. V. Chaudhari
; J. Mol. Catal.91, L1-L6, (1994)abstract
Catalysis with soluble complexes in gas-liquid-liquid systems ; R.V. Chaudhari, A. Bhattacharya and B.M. Bhanage; Catalysis Today, 24 , 123-134 (1995) abstract ; Download full paper
Enhacement of interfacial catalysis in a biphasic system using catalyst
binding ligands; R.V. Chaudhari, B.M. Bhanage, R.M. Deshpande and H.
Delmas; NATURE, 373, 501-503 (1995)abstract
Kinetics of hydroformylation of 1-dodecene using HRh(CO)(PPh3)3 complex catalyst: B.M. Bhanage, R.M. Deshpande,S.S.Divekar and R.V. Chaudhari; J. Mol. Catal., 115, 247-257 (1997) abstract ; Download full paper
Kinetics in biphasic catalysis using ethylene glycol as cosolvent
in hydroformylation of 1-hexene.; V.S.Nair, B.M. Bhanage, R.M. Deshpande
and R.V. Chaudhari; Stud. Sur. Sci. Catal.,113, 529-539 (1998)abstract
Kinetics of hydroformylation of ethylene in homogeneous organic
and aqueous systems; R.M. Deshpande, B.M. Bhanage, S.S. Divekar, S. Kanagasabapathy
and R. V. Chaudhari, Ind. & Eng. Chem. Res., 37, 2391-2396 (1998)abstract
Kinetics , R.V. Chaudhari and B.M. Bhanage Chapter in a book entitled Aqueous Phase Organometallic Catalysis Concepts and Applications Edited by B. Cornils and W.A. Herrmann , VCH Publications., Page 283-294 (1998).abstract
Heck reaction using Nickel/TPPTS catalyst and inorganic base on supported
ethylene glycol phase, B.M. Bhanage, F. –G. Zhao, M. Shirai and M. Arai,
Catal. Lett., 54, 195-198 (1998)abstract
Comparison of Activity and Selectivity of Various Metal-TPPTS Complex
Catalysts in Ethylene Glycol-Toluene Biphasic Heck Vinylation of Iodobenzene,
B.M. Bhanage, F. –G. Zhao, M. Shirai and M. Arai, Tetrahedron Lett., 39, 9509-9512 (1998) abstract ; Download full paper
A Kinetic study of Heck reaction of iodobenzene and methyl acrylate
using homogeneous Pd/TPP catalyst, F. –G. Zhao, B.M. Bhanage, M. Shirai
and M. Arai, Stud. Surf. Sci. Catal., 122, 427-430 (1998).abstract
Effect of triphenylphosphine concentration on the kinetics of homogeneous
Heck reaction in different solvents, F. –G. Zhao, B.M. Bhanage, M. Shirai
and M. Arai ; J. Mol. Catal. A, 142, 383-388 (1999) abstract ; Download full paper
Multiphase catalysis using water soluble metal complexes in supercritical
carbon dioxide, B.M. Bhanage, Y. Ikushima, M. Shirai and M. Arai, Chem. Commun., 1277-1278, (1999). abstract
Heterogeneous catalyst system for Heck reaction using supported ethylene
glycol phase Pd/TPPTS catalyst with inorganic base, B.M. Bhanage, M.
Shirai and M. Arai, J. Mol. Catal. A, 145, 69-74 (1999) abstract ; Download full paper
Heck reactions using water soluble metal complexes in supercritical
carbon dioxide, B.M. Bhanage, Y. Ikushima, M. Shirai and M. Arai, Tetrahedron letters,40, 6427-6430, (1999). abstract ; Download full paper
The Selective Formation of Unsaturated alcohols by hydrogenation of
a,b unsaturated aldehydes in supercritical carbon dioxide using unpromoted
Pt/Al2O3 catalyst, B.M. Bhanage, Y. Ikushima, M. Shirai and M. Arai, Catal. Lett., 62, 175-177, (1999).
Heck reactions using heterogeneous Pd/C catalyst system, F. –Y. Zhao,
B.M. Bhanage, M. Shirai and M. Arai, Chem. Eur. J., 6, 843-848, (2000). abstract
Sulfonation of triphenyl phosphine; B.M. Bhanage, S.S. Divekar, R.M. Deshpande and R.V. Chaudhari, Org. Proc. & Res. Dev., 4, 342-345, (2000).Download full paper
Heck reactions in supercritical carbon dioxide using organometallic
complex catalysts, B.M. Bhanage, Y. Ikushima, M. Shirai and M. Arai, High
Pressure Research, in press, (2000).
Supported liquid film catalyst and biphasic catalysis using water
soluble meHydrogenation of nitrocompounds to corresponding anilinestal complexes
in a medium of supercritical carbon dioxide, B.M. Bhanage, Y. Ikushima,
M. Shirai and M. Arai, Stud. Surf. Sci. Catal., in press, (2000).Download full paper
List of patents
An improved process for the hydroformylation of alkenes: R.V. Chaudhari, B.M. Bhanage S.S. Divekar and R.M.Deshpande; Indian Patent 758 / Del /94, (1996); U. S. Pat. No. 5498801 (1996) 8 pages abstract
An improved process for the hydrogenation of organic compounds: R.V.
Chaudhari, B.M. Bhanage, S.S. Divekar and R.M. Deshpande ; Indian Patent
701 / Del / 94; (1996); U. S. Pat. No. 5650546 (1997), 8 pages.abstract
An improved process for the hydroformylation of water soluble alkenes;
R.V. Chaudhari, B.M. Bhanage, S.S. Divekar R.M. Deshpande and V.S. Nair;
Indian Patent Appln.No. 800/Del/97 (March 1997)
An improved process for the preparation of aldehydes; R.V. abstractlvetA‘monChaudhari,
B.M. Bhanage, R.M. Deshpande and A.N. Mahajan;
Indian Patent Appln. No. 1862/Del/97 (1997)
An improved process for preparation of BPA oligomer; R.V. Chaudhari,
A.A. Kelkar, B.M. Bhanage and S. Kanagasabapathy; US Patent filed (assignee
: General Electric, USA)
An improved process for preparation of BPA oligomer; R.V. Chaudhari,
A.A. Kelkar, S. P. Gupte and B. M. Bhanage, Application filed.
Contributions in Symposium/Conferences:
(* presented by)
Role of surface active water soluble phosphine ligands in hydroformylation
of 1-dodecene using Rh-complex catalysts in homogeneous and biphasic
media ; S. K. Sabapathy, *B. M. Bhanage, S. S. Divekar and R. V. Chaudhari;
Presented at 12th National Symposium on Catalysis (CATSYMP94), Bhabha Atomic
Research Center, Bombay, (1994).
New features of hydroformylation of olefins using water soluble Rh
catalyst in a biphasic medium ; *R.V. Chaudhari, B.M. Bhanage, R.M. Deshpande,
J. Jenck, H. Delmas and Purwanto,; A paper presented at International Symposium
on Chemical Reaction Engineering (ISCRE-13) at Baltimore, USA (1994).
Catalysis with soluble complexes in gas-liquid-liquid systems ;
*R.V. Chaudhari, A. Bhattacharya and B.M. Bhanage; European Symposium on
Catalysis in multiphase reactors (549 event of the EFChE) at Lyon, France(1994).
Kinetics in biphasic catalysis using ethylene glycol as cosolvent
in hydroformylation of 1-hexene.; V.S.Nair, *B.M. Bhanage, R.M. Deshpande
and R.V. Chaudhari; 13th National Symposium on Catalysis at Dehradun,India (1997).
Kinetics of hydroformylation of ethylene in homogeneous organic
and aqueous systems; * R.M.Deshpande, B.M. Bhanage, S.S.Divekar, S.
Kanagasabapathy and R. V. Chaudhari; 'First European congress on Chemical
Engineering' Florence, Italy (1997).
Heterogeneous Heck vinylation catalysts using Pd/TPPTS immobilized
in liquid films on a silica support with inorganic bases; *B.M. Bhanage,
F. –G. Zhao, M. Shirai and M. Arai; 82nd Catalysis Society of Japan Meeting;
1998/9/16-19, Ehime University, Matsuyama, Japan.
Heck reaction using supported Pd and Ni catalysts ; B.M. Bhanage, F. –G. Zhao, M. Shirai and *M. Arai; 31st Society of Chem. Eng. Japan meeting; 1998/ 9/29-10/1, , Yamagata University, Yonezawa Japan.
Biphasic Heck reactions using Nickel/TPPTS Catalyst; *B.M. Bhanage,
F. –G. Zhao, M. Shirai and M. Arai; 40th Japan Petro. Inst. Meeting, 1998/11/16-18,
Sendai, Japan.
Heck reactions by various heterogeneous catalytic systems; *B.M. Bhanage, F. –G. Zhao, M. Shirai and M. Arai; 2nd Insitute of Chemical Reaction Science meeting, Sendai, Japan.
A Kinetic study of Heck reaction of iodobenzene and methyl acrylate
using homogeneous Pd/TPP catalyst, F. –G. Zhao, B.M. Bhanage, M. Shirai
and *M. Arai, International symposium on “Reaction Kinetic and the development
of catalytic processes” held at Brudge, Belgium, April 99.
Heck Vinylation of Iodobenzene with methyl acrylate by Pd-PPh3 Catalyst : Effects of Solvents and PPh3/Pd
Ratio; *F. –G. Zhao, B.M. Bhanage, M. Shirai and M. Arai; Catalysis Society
of Japan meeting, held at Tokyo, Japan, March 99.
Heck reactions in supercritical carbon dioxide using organometallic
complex catalysts, B.M. Bhanage, *Y. Ikushima, M. Shirai and M. Arai, 3rd
International Conference on Solvothermal Reactions (ICSTR-3) held at Bordeaux,
France, July 1999.
Selective hydrogenation of a,b unsaturated aldehydes in supercritical carbon dioxide using Pt/Al2O3 catalyst,
M. Arai*, M. Shirai, B.M. Bhanage and Y. Ikushima, 5th International
symposium on Supercritical Fluids (ISSF-2000) held at Atalanta, Georgia,
USA, April 2000.
Environmentally-benign, catalyst recyclable multiphase reaction syst4, 342-345, (2000).ems
using supercritical fluids, Bhalchandra M. Bhanage, *Masahiko Arai and Yutaka
Ikushima, The 2nd Joint Symposium between Hokkaido University and Yeungnam
University, Sapporo, Japan, August 2000.
Multiphase catalysis and separation in supercritical carbon dioxide,
Bhalchandra M. Bhanage, Yutaka Ikushima and *Masahiko Arai, International
Symposium on Supercritical Fluids for Sustainable technologies, Sendai,
Japan, August 2000. see also Proceedings of the Symposium Page 16-20.
Supported Liquid Film catalyst and Biphasic catalysis using water soluble
metal complexes in a medium of supercritical carbon dioxide, Bhalchandra
M. Bhanage*, Yutaka Ikushima, Masayuki Shirai and Masahiko Arai, International
Conference on Colloid and Surface Sciences, Tokyo, Japan, November 2000.
Ph. D. Thesis
Studies in Hydroformylation of Olefins using Transition Metal Complex
Catalysts, B. M. Bhanage, University of Poona, February, 1996 abstract
Reports
"Production and utilization of carbon monoxide and syngas from
refined petroleum coke", a report submitted to Indian Oil Corporation
Ltd, Faridabad, India under NCL-IOC collaborative work , 1210 (1996).