There are ten Big Poes in all. I'll give you the descriptions of the places where you can find the Poes. Some may be vague, some may be really detailed. I hope it helps anyway. Remember to keep an extra bottle always.
The First Poe - Located in the Northwest section of Hyrule Field. Ride around until you reveal a
Big Poe.
The Second Poe - Located at the sign right in front of Hyrule castle. Ride by the sign to reveal the
Poe.
The Third Poe - Located by the bottom of the V-Shaped wall east of Lon Lon Ranch (look at your
map). Brush by it to reveal a Big Poe.
The Fourth Poe - Located under the raised hill near Kakariko Village's entrance, near the entrance to Zora's Domain.
The Fifth Poe - Located around the southeast section of Hyrule Field. Ride around the trees until you reveal a Big Poe.
The Sixth Poe - Located around the southeast section of Hyrule Field also. Ride around until you reveal a Big Poe.
The Seventh Poe - Located right in front of the entrance to Gerudo Valley. Ride around the path on the grass until the paths cross. There, you will reveal a Big Poe.
The Eighth Poe - Located at the tree near the north end of Hyrule Field. Go by the intersecting paths until you reveal a Big Poe.
The Ninth Poe - The tree right at the entrance of Lon Lon Ranch. Ride around there until you reveal a big Poe.
The Tenth Poe - Located near the big rock where the Y-shaped path breaks. Ride around there, you'll find it. Then brush against the rock to reveal a Big Poe.