Laws of Thermodynamics

Zeroth Law and Thermal Equilibrium

This law states that if bodies A and B are each separately in thermal equilibrium with body C, then A and B are in thermal equilibrium with each other. Example.

 

First Law and Internal Energy

Change in internal energy of any system

=

heat inflow 

+

work done on the system

or, in symbols

dU

=

dQ

+

dW

 

Second law, heat engines and heat pumps

Heat Engines

No continually working heat engine can take heat from a source and convert it completely into work.
 

Heat Pumps

Heat cannot be transferred continually from one body to another at a higher temperature unless work is done by an external agent.