Researchers from Pennsylvania
State University supported by the National Science Foundation (NSF) have performed an
important step in the drive to remove environmentally harmful materials from waste streams
and drinking water. A team led by Sridhar Komarneni, professor
of clay mineralogy demonstrated that a synthetic clay known as a swelling mica has the
ability to separate ions of radium, a radioactive metal, from water. The scientists report
their results in the April 12 issue of Nature.
The finding could have implications for radioactive and hazardous
waste disposal, particularly in the cleanup of mill tailings left over from the processing
of uranium for the nation's nuclear industry. The tailings contain radium and heavy metals
that can leach into groundwater and contaminate drinking water supplies.
"This result represents significant progress in developing new
ion-separation materials," said Thomas Chapman, manager of NSF's program for
separations and purification processes, which funded the research. "With more
development, the swelling micas should prove useful in both waste remediation and metals
recovery."
The swelling mica tested by Komarneni's team, known as Na-4, is one
of a group of clays not found in the natural environment. Created specifically for water
treatment purposes, swelling micas expand as they absorb metal ions and then, reaching
their capacity, collapse and seal the contaminants inside. The swelling micas are being
explored for potential use in separating ions of heavy metals such as lead, zinc and
copper as well as other radioactive materials, including strontium, from waste streams.
Because they trap the ions, the micas can permanently immobilize the pollutants. They
could prove useful for the recovery and recycling of valuable metals as well.
Komarneni has used x-ray diffraction and nuclear magnetic resonance
spectroscopy to evaluate the chemical properties of this new class of materials. One of
his goals is to determine whether they have a larger capacity for metal uptake than
currently available materials. In this recent experiment, he succeeded in synthesizing
Na-4 into a fine powder more useful for practical applications than the large crystals
previously synthesized.
The research was performed at Penn State's Materials Research
Laboratory and Department of Agronomy.
Media contact: Amber Jones (703) 292-8070 aljones@nsf.gov
Program contact: Thomas Chapman (703) 292-8371 tchapman@nsf.gov |